
By Brett B. Palm
The year 2020 will be remembered for many reasons, including its record-breaking wildfires that turned San Francisco's skies an apocalyptic shade of red and blanketed large parts of the West in smoke for weeks on end.
California experienced five of its six largest fires on record in 2020, including the first modern "gigafire," a wildfire that burned over 1 million acres. Colorado saw its three largest fires on record.
While the smoke can make for beautiful sunsets, it can also have dire consequences for human health.
I am an atmospheric chemist, and the atmosphere is my laboratory. When I look at the sky, I see a mixture of many thousands of different chemical compounds interacting with each other and with sunlight.
The reactions and transformations in the atmosphere cause wildfire smoke to change dramatically as it travels downwind, and studies have shown that it can grow more toxic as it ages. In order to accurately forecast the effects of wildfire emissions on downwind populations and issue more-targeted air quality warnings as wildfire seasons worsen, we have to understand which chemicals are being emitted and how smoke changes with time.
To figure that out, my colleagues and I flew airplanes into the smoke plumes of some of the West's large wildfires.
How We Study Wildfires
Large wildfires and the way wind carries their smoke cannot be easily replicated in a laboratory. This makes them difficult to study. One of the best ways to learn about real wildfire smoke chemistry is to sample it directly in the atmosphere.
In 2018 and 2019, my colleagues and I crisscrossed the sky over active wildfires in specialized airplanes loaded with scientific instruments. Each instrument is designed to sample a different part of the smoke, often by literally sticking a tube out the window.
To sample smoke as it moves downwind, scientists flew back and forth across smoke plumes. The gray lines are the flights from 2018. They turn red where the path crossed a smoke plume. Brett Palm/University of Washington, CC BY-ND
Scientific aircraft used for these experiments are filled with instruments that measure wildfire smoke in different ways. Brett Palm/University of Washington, CC BY-ND
Wildfire smoke is far more complex and dynamic than meets the eye. It contains thousands of different compounds, most of which are molecules containing various amounts of carbon, hydrogen, nitrogen and oxygen atoms. There are gases (individual molecules) as well as particles (millions of molecules coagulated together).
No single instrument can measure all of these molecules at once. In fact, some specific compounds are a challenge to measure at all. Many scientists, including myself, dedicate their careers to designing and building new instruments to improve our measurements and continue to advance our understanding of the atmosphere and how it affects us.
Smoke plumes from western wildfires reached across the U.S. in mid-September 2020. Joshua Stevens/NASA Earth Observatory
In newly published research from the 2018 wildfires, my colleagues and I showed how the smoke particles changed rapidly as they were carried downwind.
Some of the particles were evaporating into gases, similar to a rain puddle evaporating into water vapor when the Sun comes out. At the same time, some of the gases in smoke were going through reactions to form new particles, similar to water vapor condensing to form a cloud or dew droplets. Meanwhile, chemical reactions were occurring, changing the molecules themselves.
As these molecules reacted with sunlight and other gases in the atmosphere, the smoke was fundamentally transformed. This is what we mean when scientists talk about smoke "aging" or getting "stale" over time. Other recent research has started to show how wildfire smoke can become more toxic as it ages.
What Do All These Changes Mean for Health?
The health damage from smoke is largely a result of how much PM2.5 it contains. These are tiny particles, a fraction of the width of a human hair, that can be breathed deep into the lungs where they can irritate the respiratory tract. Even short-term exposure can aggravate heart and lung problems.
PM2.5 particles are tiny at less than 2.5 microns across. U.S. Environmental Protection Agency
Chemical reactions control how much PM2.5 is in wildfire smoke as it is transported away from the fires and into population centers. Using our aircraft measurements to understand these processes, we chemists can better predict how much PM2.5 will be present in aged smoke.
Combined with meteorology forecasting that predicts where the smoke will go, this could lead to improved air quality models that can tell people downwind whether they will be exposed to unhealthy air.
Better Air Quality Forecasting
With wildfires increasingly in the news, more people have become aware of their own air quality. Resources such as AirNow from the U.S. Environmental Protection Agency provide current and forecasted air quality data, along with explanations of the health hazards. Local information is often available from state or regional agencies as well.
Air quality measurements and forecasts can help people avoid unhealthy situations, especially sensitive groups such as people with asthma. During predicted periods of unhealthy air quality, local or state governments can use forecasts to reduce other pollution sources, such as discouraging residential wood burning or high-emitting industrial activities.
Looking to the future, wildfire smoke is likely to be widespread across the West each year for several reasons. Rising temperatures are leaving the landscape drier and more flammable. At the same time, more people are building homes in the wildland-urban interface, creating more opportunities for fires to start.
A large community of scientists including me are working to better understand wildfire emissions and how they change as they blow into downwind communities. That knowledge will improve forecasts for air quality and health impacts of wildfire smoke, so people can learn to adapt and avoid the worst health consequences.
Brett B. Palm is a Postdoctoral Researcher in Atmospheric Chemistry, University of Washington.
Disclosure statement: Brett Palm receives funding from the National Science Foundation and the National Oceanic and Atmospheric Administration.
Reposted with permission from The Conversation.
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By Lynne Peeples
Editor's note: This story is part of a nine-month investigation of drinking water contamination across the U.S. The series is supported by funding from the Park Foundation and Water Foundation. Read the launch story, "Thirsting for Solutions," here.
In late September 2020, officials in Wrangell, Alaska, warned residents who were elderly, pregnant or had health problems to avoid drinking the city's tap water — unless they could filter it on their own.
Unintended Consequences
<p>Chemists first discovered disinfection by-products in treated drinking water in the 1970s. The trihalomethanes they found, they determined, had resulted from the reaction of chlorine with natural organic matter. Since then, scientists have identified more than 700 additional disinfection by-products. "And those only represent a portion. We still don't know half of them," says Richardson, whose lab has identified hundreds of disinfection by-products. </p>What’s Regulated and What’s Not?
<p>The U.S. Environmental Protection Agency (EPA) currently regulates 11 disinfection by-products — including a handful of trihalomethanes (THM) and haloacetic acids (HAA). While these represent only a small fraction of all disinfection by-products, EPA aims to use their presence to indicate the presence of other disinfection by-products. "The general idea is if you control THMs and HAAs, you implicitly or by default control everything else as well," says Korshin.</p><p>EPA also requires drinking water facilities to use techniques to reduce the concentration of organic materials before applying disinfectants, and regulates the quantity of disinfectants that systems use. These rules ultimately can help control levels of disinfection by-products in drinking water.</p>Click the image for an interactive version of this chart on the Environmental Working Group website.
<p>Still, some scientists and advocates argue that current regulations do not go far enough to protect the public. Many question whether the government is regulating the right disinfection by-products, and if water systems are doing enough to reduce disinfection by-products. EPA is now seeking public input as it considers potential revisions to regulations, including the possibility of regulating additional by-products. The agency held a <a href="https://www.epa.gov/dwsixyearreview/potential-revisions-microbial-and-disinfection-byproducts-rules" target="_blank">two-day public meeting</a> in October 2020 and plans to hold additional public meetings throughout 2021.</p><p>When EPA set regulations on disinfection by-products between the 1970s and early 2000s, the agency, as well as the scientific community, was primarily focused on by-products of reactions between organics and chlorine — historically the most common drinking water disinfectant. But the science has become increasingly clear that these chlorinated chemicals represent a fraction of the by-product problem.</p><p>For example, bromide or iodide can get caught up in the reaction, too. This is common where seawater penetrates a drinking water source. By itself, bromide is innocuous, says Korshin. "But it is extremely [reactive] with organics," he says. "As bromide levels increase with normal treatment, then concentrations of brominated disinfection by-products will increase quite rapidly."</p><p><a href="https://pubmed.ncbi.nlm.nih.gov/15487777/" target="_blank">Emerging</a> <a href="https://pubs.acs.org/doi/10.1021/acs.est.7b05440" target="_blank" rel="noopener noreferrer">data</a> indicate that brominated and iodinated by-products are potentially more harmful than the regulated by-products.</p><p>Almost half of the U.S. population lives within 50 miles of either the Atlantic or Pacific coasts, where saltwater intrusion can be a problem for drinking water supplies. "In the U.S., the rule of thumb is the closer to the sea, the more bromide you have," says Korshin, noting there are also places where bromide naturally leaches out from the soil. Still, some coastal areas tend to be spared. For example, the city of Seattle's water comes from the mountains, never making contact with seawater and tending to pick up minimal organic matter.</p><p>Hazardous disinfection by-products can also be an issue with desalination for drinking water. "As <a href="https://ensia.com/features/can-saltwater-quench-our-growing-thirst/" target="_blank" rel="noopener noreferrer">desalination</a> practices become more economical, then the issue of controlling bromide becomes quite important," adds Korshin.</p>Other Hot Spots
<p>Coastal areas represent just one type of hot spot for disinfection by-products. Agricultural regions tend to send organic matter — such as fertilizer and animal waste — into waterways. Areas with warmer climates generally have higher levels of natural organic matter. And nearly any urban area can be prone to stormwater runoff or combined sewer overflows, which can contain rainwater as well as untreated human waste, industrial wastewater, hazardous materials and organic debris. These events are especially common along the East Coast, notes Sydney Evans, a science analyst with the nonprofit Environmental Working Group (EWG, a collaborator on <a href="https://ensia.com/ensia-collections/troubled-waters/" target="_blank">this reporting project</a>).</p><p>The only drinking water sources that might be altogether free of disinfection by-products, suggests Richardson, are private wells that are not treated with disinfectants. She used to drink water from her own well. "It was always cold, coming from great depth through clay and granite," she says. "It was fabulous."</p><p>Today, Richardson gets her water from a city system that uses chloramine.</p>Toxic Treadmill
<p>Most community water systems in the U.S. use chlorine for disinfection in their treatment plant. Because disinfectants are needed to prevent bacteria growth as the water travels to the homes at the ends of the distribution lines, sometimes a second round of disinfection is also added in the pipes.</p><p>Here, systems usually opt for either chlorine or chloramine. "Chloramination is more long-lasting and does not form as many disinfection by-products through the system," says Steve Via, director of federal relations at the American Water Works Association. "Some studies show that chloramination may be more protective against organisms that inhabit biofilms such as Legionella."</p>Alternative Approaches
<p>When he moved to the U.S. from Germany, Prasse says he immediately noticed the bad taste of the water. "You can taste the chlorine here. That's not the case in Germany," he says.</p><p>In his home country, water systems use chlorine — if at all — at lower concentrations and at the very end of treatment. In the Netherlands, <a href="https://dwes.copernicus.org/articles/2/1/2009/dwes-2-1-2009.pdf" target="_blank">chlorine isn't used at all</a> as the risks are considered to outweigh the benefits, says Prasse. He notes the challenge in making a convincing connection between exposure to low concentrations of disinfection by-products and health effects, such as cancer, that can occur decades later. In contrast, exposure to a pathogen can make someone sick very quickly.</p><p>But many countries in Europe have not waited for proof and have taken a precautionary approach to reduce potential risk. The emphasis there is on alternative approaches for primary disinfection such as ozone or <a href="https://www.pbs.org/wgbh/nova/article/eco-friendly-way-disinfect-water-using-light/" target="_blank" rel="noopener noreferrer">ultraviolet light</a>. Reverse osmosis is among the "high-end" options, used to remove organic and inorganics from the water. While expensive, says Prasse, the method of forcing water through a semipermeable membrane is growing in popularity for systems that want to reuse wastewater for drinking water purposes.</p><p>Remucal notes that some treatment technologies may be good at removing a particular type of contaminant while being ineffective at removing another. "We need to think about the whole soup when we think about treatment," she says. What's more, Remucal explains, the mixture of contaminants may impact the body differently than any one chemical on its own. </p><p>Richardson's preferred treatment method is filtering the water with granulated activated carbon, followed by a low dose of chlorine.</p><p>Granulated activated carbon is essentially the same stuff that's in a household filter. (EWG recommends that consumers use a <a href="https://www.ewg.org/tapwater/reviewed-disinfection-byproducts.php#:~:text=EWG%20recommends%20using%20a%20home,as%20trihalomethanes%20and%20haloacetic%20acids." target="_blank" rel="noopener noreferrer">countertop carbon filter</a> to reduce levels of disinfection by-products.) While such a filter "would remove disinfection by-products after they're formed, in the plant they remove precursors before they form by-products," explains Richardson. She coauthored a <a href="https://pubs.acs.org/doi/10.1021/acs.est.9b00023" target="_blank" rel="noopener noreferrer">2019 paper</a> that concluded the treatment method is effective in reducing a wide range of regulated and unregulated disinfection by-products.</p><br>Greater Cincinnati Water Works installed a granulated activated carbon system in 1992, and is still one of relatively few full-scale plants that uses the technology. Courtesy of Greater Cincinnati Water Works.
<p>Despite the technology and its benefits being known for decades, relatively few full-scale plants use granulated active carbon. They often cite its high cost, Richardson says. "They say that, but the city of Cincinnati [Ohio] has not gone bankrupt using it," she says. "So, I'm not buying that argument anymore."</p><p>Greater Cincinnati Water Works installed a granulated activated carbon system in 1992. On a video call in December, Jeff Swertfeger, the superintendent of Greater Cincinnati Water Works, poured grains of what looks like black sand out of a glass tube and into his hand. It was actually crushed coal that has been baked in a furnace. Under a microscope, each grain looks like a sponge, said Swertfeger. When water passes over the carbon grains, he explained, open tunnels and pores provide extensive surface area to absorb contaminants.</p><p>While the granulated activated carbon initially was installed to address chemical spills and other industrial contamination concerns in the Ohio River, Cincinnati's main drinking water source, Swertfeger notes that the substance has turned out to "remove a lot of other stuff, too," including <a href="https://ensia.com/features/drinking-water-contamination-pfas-health/" target="_blank" rel="noopener noreferrer">PFAS</a> and disinfection by-product precursors.</p><p>"We use about one-third the amount of chlorine as we did before. It smells and tastes a lot better," he says. "The use of granulated activated carbon has resulted in lower disinfection by-products across the board."</p><p>Richardson is optimistic about being able to reduce risks from disinfection by-products in the future. "If we're smart, we can still kill those pathogens and lower our chemical disinfection by-product exposure at the same time," she says.</p><p><em>Reposted with permission from </em><em><a href="https://ensia.com/features/drinking-water-disinfection-byproducts-pathogens/" target="_blank">Ensia</a>. </em><a href="https://www.ecowatch.com/r/entryeditor/2649953730#/" target="_self"></a></p>EcoWatch Daily Newsletter
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Earth had its second-warmest year on record in 2020, just 0.02 degrees Celsius (0.04°F) behind the record set in 2016, and 0.98 degrees Celsius (1.76°F) above the 20th-century average, NOAA reported January 14.
Figure 1. Departure of temperature from average for 2020, the second-warmest year the globe has seen since record-keeping began in 1880, according to NOAA. Record-high annual temperatures over land and ocean surfaces were measured across parts of Europe, Asia, southern North America, South America, and across parts of the Atlantic, Indian, and Pacific oceans. No land or ocean areas were record cold for the year. NOAA National Centers for Environmental Information
Figure 2. Total ocean heat content (OHC) in the top 2000 meters from 1958-2020. Cheng et al., Upper Ocean Temperatures Hit Record High in 2020, Advances in Atmospheric Sciences
Figure 3. Departure of sea surface temperature from average in the benchmark Niño 3.4 region of the eastern tropical Pacific (5°N-5°S, 170°W-120°W). Sea surface temperature were approximately one degree Celsius below average over the past month, characteristic of moderate La Niña conditions. Tropical Tidbits
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