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Dangerous Metals Found in Latest Duke Energy Coal Ash Spill
The record-breaking flood of the Neuse River inundated three inactive coal ash ponds for five days last week from the Duke Energy H.F. Lee facility, 10 miles upstream of Goldsboro, North Carolina. The flooded ponds are unlined and uncovered, containing more than 1 million tons of coal ash spread over more than 170 acres in a layer 4 to 10 feet deep.
On Oct. 14 at 4:28 p.m., before the flood waters had completely receded from the flooded ash ponds, Duke Energy reported a spill of an undetermined amount of coal ash into the Neuse River to the U.S. Coast Guard's National Response Center. On Oct. 15, Duke Energy and the North Carolina Department of Environmental Quality personnel inspected the inactive ash ponds by foot, claiming they "determined that the amount of material that was displaced would not even fill the bed of an average pickup truck."
On Oct. 17, the flood waters had receded enough to allow the Waterkeeper Alliance rapid response team to launch a boat in the Neuse River to inspect for coal ash releases. Later that afternoon, the Upper Neuse Riverkeeper discovered a second coal ash spill coming from the inactive ash ponds at HF Lee. The coating of ash on tree branches high above the receding flood waters proved the spill had been ongoing for almost a week.
Duke Energy and DEQ claim their representatives identified the second spill on Oct. 17 as well, independent of Waterkeeper Alliance's public disclosure of the spill on Oct. 18. The Waterkeeper Alliance rapid response team questions the claim that both DEQ inspectors and Duke Energy staff traveled to the location of the second spill by boat on Oct. 17 and identified the white substance floating on the water and coating the trees.
To the contrary, Duke Energy reportedly told WNCN on the evening of Oct. 18 that it had not yet conducted water sampling from a boat because state regulators had not deemed it safe to boat on the flooded river. This directly contradicts subsequent claims by Duke and DEQ that they had observed the spill by boat on Oct. 17.
"The agency that should be a watchdog protecting the public is acting more like a PR firm trying to protect Duke Energy's reputation," Waterkeeper Alliance attorney Pete Harrison said. "This is the same agency that only a year ago stood up in court and tried to block an agreement between Waterkeeper and Duke that requires Duke to remove all the coal ash from the ash ponds that flooded."
Since we exposed the second spill on the afternoon of Oct. 18, Duke Energy has continued to insist that the spilled material is "not coal ash," falsely claiming that cenospheres are distinct from fly ash, the primary constituent of coal ash.
However, scientists at Appalachian State University used a scanning electron microscope (SEM) to visualize samples of the spilled coal ash cenospheres, and tested the particles for contaminants using Energy-dispersive X-ray spectroscopy (EDX).
The EDX analysis detected dangerous heavy metals attached to the fly ash cenospheres, including antimony and cobalt.
Scanning electron microscope (SEM) image of coal ash cenosphere found in Neuse River on Oct. 17.Dr. Guichuan Hou, PhD, Director of Dewel Microscopy Facility, Research Associate Professor of Biology, Appalachian State University
Energy-dispersive X-ray spectroscopy (EDX) graph of chemicals in or on a coal ash cenosphere that was found in the Neuse River on Oct. 17. The analysis detected antimony, cobalt, and thallium, which can be toxic to people and aquatic life.Dr. Guichuan Hou, PhD, Director of Dewel Microscopy Facility, Research Associate Professor of Biology, Appalachian State University
Duke Energy has previously reported elevated levels of both these contaminants in groundwater monitoring wells located around the inactive ash ponds where the coal ash spill occurred. Throughout the week, Duke Energy attempted to characterize cenospheres as "not coal ash" and "inert" and "not inherently toxic." These talking points carefully avoid acknowledging what the EDX analysis confirms: the spilled coal ash cenospheres, though composed largely out of silica and aluminum, have more dangerous contaminants attached to them.
Harrison called the mischaracterization "a shameful attempt by Duke Energy to trick the public and cover up a large coal ash spill that the company failed to identify and/or failed to report."
Duke Energy even acknowledges on its website that "cenospheres are a form of fly ash." Duke's failure to report the spill may have even been a violation of the company's probation sentence, which it received last year after pleading guilty to federal crimes involving its mismanagement of coal ash at the H.F. Lee facility, among others.
Because Duke Energy did report a spill of coal ash on Oct. 14 (the purported pickup truck load), and the company has emphatically denied that the material discovered by the Upper Neuse Riverkeeper is coal ash, it is clear that material discovered in the river on Oct. 17 was a separate and distinct spill from the one Duke Energy reported on Oct. 14. Based on currently available information, Duke Energy has still not reported the second spill to then National Response Center.
On Oct. 19, the day after our organizations exposed the second coal ash spill, the DEQ claimed its "staff determined on Monday that material found at the H.F. Lee facility in Wayne County is not coal ash," and accused Waterkeeper Alliance of "falsely reporting" the coal ash release. Both Duke and DEQ claimed, without analyzing the spilled material, that it was harmless cenospheres comprised of just aluminum and silica.
"After adopting Duke Energy's indefensible position that the material was not coal ash and requiring no further action from Duke on Wednesday, DEQ has now done an about face, admitting last night that cenospheres are fly ash and ordering Duke to investigate the spills further," Matthew Starr, Sound Rivers' Upper Neuse Riverkeeper, said.
"The DEQ bureaucrats must have woken up yesterday with the embarrassing realization that the state Coal Ash Management Act they're in charge of implementing defines cenospheres as coal ash," Donna Lisenby of Waterkeeper Alliance said.
"Now DEQ seems to be changing its tune and agreeing with what we've been saying all along: Duke Energy is responsible for another coal ash spill into the Neuse River. Unfortunately this one looks like a lot more than a pickup-truck's worth of ash was spilled."
EcoWatch Daily Newsletter
By Tom Duszynski
The coronavirus is certainly scary, but despite the constant reporting on total cases and a climbing death toll, the reality is that the vast majority of people who come down with COVID-19 survive it. Just as the number of cases grows, so does another number: those who have recovered.
In mid-March, the number of patients in the U.S. who had officially recovered from the virus was close to zero. That number is now in the tens of thousands and is climbing every day. But recovering from COVID-19 is more complicated than simply feeling better. Recovery involves biology, epidemiology and a little bit of bureaucracy too.
How does your body fight off COVID-19?<p>Once a person is exposed the coronavirus, the body starts producing <a href="https://www.mblintl.com/products/what-are-antibodies-mbli/" target="_blank">proteins called antibodies to fight the infection</a>. As these <a href="https://www.statnews.com/2020/03/27/serological-tests-reveal-immune-coronavirus/" target="_blank">antibodies start to successfully contain the virus</a> and keep it from replicating in the body, symptoms usually begin to lessen and you start to feel better. Eventually, if all goes well, your immune system will completely destroy all of the virus in your system. A person who was infected with and survived a virus with no long-term health effects or disabilities has "recovered."</p><p>On average, a person who is infected with SARS-CoV-2 will feel ill for about seven days from the onset of symptoms. Even after symptoms disappear, there still may be small amounts of the virus in a patient's system, and they should stay <a href="https://www.cdc.gov/coronavirus/2019-ncov/if-you-are-sick/steps-when-sick.html" target="_blank">isolated for an additional three days</a> to ensure they have truly <a href="https://health.usnews.com/conditions/articles/coronavirus-recovery-what-to-know" target="_blank">recovered and are no longer infectious</a>.</p>
What about immunity?<p>In general, once you have recovered from a viral infection, your body will keep cells called lymphocytes in your system. These cells "remember" viruses they've previously seen and can react quickly to fight them off again. If you are exposed to a virus you have already had, your antibodies will likely stop the virus before it starts causing symptoms. <a href="https://dx.doi.org/10.5114%2Fceji.2018.77390" target="_blank">You become immune</a>. This is the <a href="https://www.ncbi.nlm.nih.gov/books/NBK27158/" target="_blank">principle behind many vaccines</a>.</p><p>Unfortunately, immunity isn't perfect. For many viruses, like mumps, immunity can wane over time, leaving you <a href="https://www.sciencedaily.com/releases/2016/04/160421145747.htm" target="_blank">susceptible to the virus in the future</a>. This is why you need to get revaccinated – those "booster shots" – occasionally: to prompt your immune system to make more antibodies and memory cells.</p><p>Since this coronavirus is so new, scientists still don't know whether people who recover from COVID-19 are <a href="https://www.cdc.gov/coronavirus/2019-ncov/hcp/faq.html" target="_blank">immune to future infections of the virus</a>. Doctors are finding antibodies in ill and recovered patients, and <a href="https://www.cdc.gov/coronavirus/2019-ncov/hcp/clinical-guidance-management-patients.html" target="_blank">that indicates the development of immunity</a>. But the question remains how long that immunity will last. Other coronaviruses like <a href="https://doi.org/10.1002/jmv.25685" target="_blank">SARS and MERS produce an immune response</a> that will protect a person at least for a short time. I would suspect the same is true of SARS-CoV-2, but the research simply hasn't been done yet to say so definitively.</p>
Why have so few people officially recovered in the US?<p>This is a dangerous virus, so the Centers for Disease Control and Prevention is being extremely careful when deciding what it means to recover from COVID-19. Both medical and testing criteria must be met before a person is <a href="https://www.cdc.gov/coronavirus/2019-ncov/hcp/disposition-in-home-patients.html" target="_blank">officially declared recovered</a>.</p><p>Medically, a person must be fever-free without fever-reducing medications for three consecutive days. They must show an improvement in their other symptoms, including reduced coughing and shortness of breath. And it must be at least seven full days <a href="https://health.usnews.com/conditions/articles/coronavirus-recovery-what-to-know" target="_blank">since the symptoms began</a>.</p><p>In addition to those requirements, the CDC guidelines say that a person must test negative for the coronavirus twice, with the <a href="https://www.cdc.gov/coronavirus/2019-ncov/if-you-are-sick/care-for-someone.html" target="_blank">tests taken at least 24 hours apart</a>.</p><p>Only then, if both the symptom and testing conditions are met, is a person officially considered recovered by the CDC.</p><p>This second testing requirement is likely why there were so few official recovered cases in the U.S. until late March. Initially, there was a <a href="https://www.nytimes.com/2020/03/18/health/coronavirus-test-shortages-face-masks-swabs.html" target="_blank">massive shortage of testing in the U.S.</a> So while many people were certainly recovering over the last few weeks, this could not be officially confirmed. As the country enters the height of the pandemic in the coming weeks, focus is still on <a href="https://www.cdc.gov/coronavirus/2019-nCoV/hcp/clinical-criteria.html" target="_blank">testing those who are infected</a>, not those who have likely recovered.</p><p>Many more people are being tested now that states and private companies have begun <a href="https://www.cdc.gov/coronavirus/2019-ncov/cases-updates/testing-in-us.html" target="_blank">producing and distributing tests</a>. As <a href="https://www.dispatch.com/news/20200406/coronavirus-in-ohio-from-its-rocky-start-testing-for-covid-19-slowly-ramping-up" target="_blank">the number of available tests increases</a> and the pandemic eventually slows in the country, more testing will be available for those who have appeared to recover. As people who have already recovered are tested, the appearance of any new infections will help researchers learn <a href="https://www.statnews.com/2020/03/24/we-need-smart-coronavirus-testing-not-just-more-testing/" target="_blank">how long immunity can be expected to last</a>.</p>
Once a person has recovered, what can they do?<p>Knowing whether or not people are immune to COVID-19 after they recover is going to determine what individuals, communities and society at large can do going forward. If scientists can show that recovered patients are immune to the coronavirus, then a person who has recovered could in theory <a href="https://www.vox.com/2020/3/30/21186822/immunity-to-covid-19-test-coronavirus-rt-pcr-antibody" target="_blank">help support the health care system</a> by caring for those who are infected.</p><p>Once communities pass the peak of the epidemic, the number of new infections will decline, while the number of <a href="https://www.newsweek.com/china-says-passed-peak-coronavirus-epidemic-covid-19-1491863" target="_blank">recovered people will increase</a>. As these trends continue, the risk of transmission will fall. Once the risk of transmission has fallen enough, community-level isolation and social distancing orders will begin to relax and businesses will start to reopen. Based on what other countries have gone through, it will be <a href="https://www.nature.com/articles/d41586-020-00154-w" target="_blank">months until the risk of transmission is low</a> in the U.S.</p><p>But before any of this can happen, the U.S. and the world need to make it through the peak of this pandemic. Social distancing works to slow the spread of infectious diseases and <a href="https://www.cdc.gov/coronavirus/2019-ncov/need-extra-precautions/what-you-can-do.html" target="_blank">is working for COVID-19</a>. Many people will <a href="https://www.yalemedicine.org/stories/2019-novel-coronavirus/" target="_blank">need medical help to recover</a>, and social distancing will slow this virus down and give people the best chance to do so.</p>
By Elizabeth Claire Alberts
The future for the world's oceans often looks grim. Fisheries are set to collapse by 2048, according to one study, and 8 million tons of plastic pollute the ocean every year, causing considerable damage to delicate marine ecosystems. Yet a new study in Nature offers an alternative, and more optimistic view on the ocean's future: it asserts that the entire marine environment could be substantially rebuilt by 2050, if humanity is able to step up to the challenge.
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By Zulfikar Abbany
Bread has been a source of basic nutrition for centuries, the holy trinity being wheat, maize and rice. It has also been the reason for a lot of innovation in science and technology, from millstones to microbiological investigations into a family of single-cell fungi called Saccharomyces.
Chemical leavening<p>If you like a little heft in your loaf, you will need a leavening agent.</p><p>For those short on time, you can use baking soda. That's a chemical compound of sodium bicarbonate mixed with potassium bitartrate, or cream of tartar.</p><p>Soda breads have their traditions in parts of eastern and central Europe, and in Ireland and Scotland, with Melrose loaves and "farls."</p><p>They can taste a bit bland, though, and are often considered only as an emergency solution on Sundays. No disrespect intended: They taste just fine fresh from the oven.</p><p>Whether it's chemical or more "natural," leavening relies largely on the production of carbon dioxide.</p><p>When you mix an acid, such as vinegar, buttermilk, yogurt or apple cider, with an alkaline compound like baking soda, you get CO2. That CO2 creates bubbles, which in turn capture steam in the oven and allow a bread to rise.</p><p><span></span>But it's better with yeast. Tastes better, too. It just takes more time. </p>
What is yeast?<p>There are yeasts all around us — on grains, in the air, in biofuels. It even lives inside us, but that's not always a good thing.</p><p><a href="https://www.ncbi.nlm.nih.gov/pmc/articles/PMC1090575/pdf/1471-2334-5-22.pdf" target="_blank">Candida yeast</a> can cause infections of the skin, feet, mouth, penis or vagina if it builds up too much in the body.</p><p>One of the most common yeasts, however, is <em>Saccharomyces cerevisiae</em>. That's <a href="https://www.dw.com/en/an-early-beer-archaeologists-tap-ground-at-worlds-oldest-brewery/a-45480731" target="_blank">"brewer's"</a> or "baker's" yeast.</p><p>You can get fresh baker's yeast, often in 42-gram (1.48-ounce) cubes, or as dried yeast (quick action or active, which requires rehydration) in a sachet of 7 grams.</p><p>There's little difference: One is compressed and the other is dehydrated and granulated. But they do the same thing, essentially. </p><p>Some commercial yeast producers add molasses and other nutrients. But natural yeast has plenty of useful nutrients in it anyway, including B group vitamins, so who knows whether it's good or necessary to add them. </p>
How does yeast work?<p>When you mix flour, yeast and water, you set off a veritable chain reaction. Enzymes in the wheat convert starch into sugar. And the yeast creates enzymes of its own to convert those sugars into a form it can absorb.</p><p>The yeast "feeds" on the sugars to create carbon dioxide and alcohol. The yeast burps and farts, releasing gases into the mix, and that creates bubbles to trap CO2. </p><p>It's a vital fermentation process that breaks down the gluten in the flour and helps make your bread more digestible.</p><p>The yeast cells split and reproduce, generating lactic and carbonic acid, raising the temperature and ultimately adding flavor to the mix.</p><p>The longer you leave the yeast to do its thing, the better for your bread. Time is more important than the amount of yeast. </p><p>In fact, that's an enduring question — how much yeast? I'll use 20 grams fresh yeast for 500 grams of flour. Others say that's enough yeast for 1 kilo. If you are converting a dry-yeast recipe to fresh yeast, some bakers advise tripling the weight. So, if a sachet of dried yeast is 7 grams, your fresh yeast is 21 grams.</p><p><span></span>But that also depends on the flours you are using, temperatures in the bowl and the room, and a host of other things. You'll just have to experiment and see. No number of books (and I've read a stack on bread) will help as much as trial and error.</p>
Wild yeast: Sourdough<p>So, good bread needs time. If you have a lot of time, why not move it up a notch and grow wild yeast — a sourdough starter — in your own home?</p><p>A sourdough starter is not to be mistaken (as it often is) for the leaven, or "mother," "sponge," or <em>levain</em>. That's more a second stage, a descendant of the starter. You take a scoop from your starter and add it to another flour and water mixture when you prepare the dough for a new loaf. </p><p>The sourdough process utilizes yeasts naturally present in flour and … yet more time. A longer fermentation process allows a richer lactic acid bacteria <em>lactobacilli</em> or LAB to evolve, and that can be healthy for your gut microbiome.</p><p>It's simple enough to start a sourdough starter. All you need is flour, warm water and time.</p><p>Some suggest equal measures of whole-grain flour and water at 28 degrees Celsius (82 degrees Fahrenheit), some say room temperature — just don't let the water exceed 40 C or the yeasts will die. Some suggest two parts flour to three parts water. But it's up to you whether you want a drier or wetter starter. You will know only through experimentation. </p><p>Some say you should filter tap water to remove chemicals like fluoride and avoid using water that's boiled and then cooled. Others say that really doesn't matter.</p><p>The main thing is, keep it clean and give it time. Days, weeks, months and years.</p>
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