Silver Nanoparticles in Clothing Wash Out, May Be Toxic
By Sukalyan Sengupta and Tabish Nawaz
Humans have known since ancient times that silver kills or stops the growth of many microorganisms. Hippocrates, the father of medicine, is said to have used silver preparations for treating ulcers and healing wounds. Until the introduction of antibiotics in the 1940s, colloidal silver (tiny particles suspended in a liquid) was a mainstay for treating burns, infected wounds and ulcers. Silver is still used today in wound dressings, in creams and as a coating on medical devices.
Since the 1990s, manufacturers have added silver nanoparticles to numerous consumer products to enhance their antibacterial and anti-odor properties. Examples include clothes, towels, undergarments, socks, toothpaste and soft toys. Nanoparticles are ultra-small particles, ranging from 1 to 100 nanometers in diameter—too small to see even with a microscope. According to a widely cited database, about one-fourth of nanomaterial-based consumer products currently marketed in the U.S. contain nanosilver.
Korean toothpaste containing nanosilver Alex Parlini, Project on Emerging Nanotechnologies, CC BY-ND
Multiple studies have reported that nanosilver leaches out of textiles when they are laundered. Research also reveals that nanosilver may be toxic to humans and aquatic and marine organisms. Although it is widely used, little is understood about its fate or long-term toxic effects in the environment.
We are developing ways to convert this potential ecological crisis into an opportunity by recovering pure silver nanoparticles, which have many industrial applications, from laundry wastewater. In a recently published study, we describe a technique for silver recovery and discuss the key technical challenges. Our approach tackles this problem at the source—in this case, individual washing machines. We believe that this strategy has great promise for getting newly identified contaminants out of wastewater.
A Textile Silver Lode
Use of nanosilver in consumer products has steadily risen in the past decade. The market share of silver-based textiles rose from 9 percent in 2004 to 25 percent in 2011.
Several investigators have measured the silver content of textiles and found values ranging from 0.009 to 21,600 milligrams of silver per kilogram of textile. Studies show that the amount of silver leached in the wash solution depends on many factors, including interactions between detergent and other chemicals and how silver is attached to the textiles.
In humans, exposure to silver can harm liver cells, skin and lungs. Prolonged exposure or exposure to a large dose can cause a condition called argyria, in which the victim's skin turns permanently bluish-gray.
Toxic effects of silver nanoparticles on zebra fish embryos Asharani et al., 2008., CC BY
Once silver goes down the drain and ends up at wastewater treatment plants, it can potentially harm bacterial treatment processes, making them less efficient, and foul treatment equipment. More than 90 percent of silver nanoparticles released in wastewater end up in nutrient-rich biosolids left over at the end of sewage treatment, which often are used on land as agricultural fertilizers.
This poses multiple risks. If plants take up silver from soil, they could concentrate it and introduce it into the food chain. It also can leach into groundwater or wash into rivers via rainstorms or erosion.
Treating Laundry Water at the Source
Our research shows that the most efficient way to remove silver from wastewater is by treating it in the washing machine. At this point silver concentrations are relatively high, and silver is initially released from treated clothing in a chemical form that is feasible to recover.
Once laundry washwater is piped to wastewater treatment plants and mixed with sewage and water from other sources, silver concentrations decrease significantly and can be converted into different chemical forms.
Deer Island Wastewater Treatment Plant, Boston, Massachusetts Doc Searls, CC BY
A bit of chemistry is helpful here. Our recovery method employs a widely used chemistry process called ion exchange. Ions are atoms or molecules that have an electrical charge. In ion exchange, a solid and a liquid are brought together and exchange ions with each other.
For example, household soaps do not lather well in "hard" water, which contains high levels of ions such as magnesium and calcium. Many home water filters use ion exchange to "soften" the water, replacing those materials with other ions that do not affect its properties in the same way.
For this process to work, the ions that switch places must both be either positively or negatively charged. Nanosilver is initially released from textiles as silver ion, which is a cation—an ion with a positive charge (hence the plus sign in its chemical symbol, Ag+).
Even at the source, removing silver from washwater is challenging. Silver concentrations in the wash solution are relatively low compared to other cations, such as calcium, that could interfere with the removal process. Detergent chemistry complicates the picture further because some detergent components can potentially interact with silver.
To recover silver without picking up other chemicals, the recovery process must use materials that have a chemical affinity for silver. In a previous study, we described a potential solution: Using ion-exchange materials embedded with sulfur-based chemicals, which bind preferentially with silver.
In our new study, we passed washwater through an ion-exchange resin column and analyzed how each major detergent ingredient interacted with silver in the water and affected the resin's ability to remove silver from the water. By manipulating process conditions such as pH, temperature and concentration of nonsilver cations, we were able to identify conditions that maximized silver recovery.
Schematic of the silver recovery process using ion-exchange resinTabish Nawaz
We found that pH and the levels of calcium ions (Ca2+) were critical factors. Higher levels of hydrogen or calcium ions bind up detergent ingredients and prevent them from interacting with silver ions, so the ion-exchange resin can remove the silver from the solution. We also found that some detergent ingredients—particularly bleaching and water-softening agents—made the ion-exchange resin work less efficiently. Depending on these conditions, we recovered between 20 percent and 99 percent of the silver in the washwater.
Our findings can spur research into alternative detergent formulations that improve silver recovery. They also show that ion-exchange technology can recover trace silver from washwater that contains high levels of detergent.
The Future of Wastewater Treatment
Today wastewater is collected from multiple sources, such as homes and businesses, and piped over long distances to centralized wastewater treatment plants. But increasing evidence shows that these facilities are ill-equipped to keep newly identified contaminants out of the environment, since they use one common treatment scheme for many different waste streams.
We believe the future is in decentralized systems that can treat different types of wastewater with specific technologies designed specifically for the materials they contain. If wastewater from laundromats contains different contaminants than wastewater from restaurants, why treat them the same way?
Our approach is both more efficient and a more effective way to address new environmental problems—potentially through a step as simple as installing a specialized water treatment cartridge in your washing machine.
Are Dryer Sheets and Liquid Softeners Safe for the Environment? https://t.co/NTK3QGK1RG @CleanAirMoms @ewg @goodhealth— EcoWatch (@EcoWatch)1519666753.0
Reposted with permission from our media associate The Conversation.
EcoWatch Daily Newsletter
By Zahida Sherman
Cooking has always intimidated me. As a child, I would anxiously peer into the kitchen as my mother prepared Christmas dinner for our family.
Falling in Love With Food All Over Again<p>Slowly, through my most intimate relationships with friends and partners, I began to see the beauty — and rewards — of cooking.</p><p>I got tired of giving in to defeat and always bringing chips or paper products to social gatherings. I started asking my mom to send me her Christmas and Thanksgiving recipes. I even volunteered to host Thanksgiving dinner at my place.</p><p>Each time I heard my loved ones sing the praises of the foods I prepared for them, I felt a tinge more confident that I could carry out our traditions my way.</p><p>In reaching out to other relatives for their favorite recipes, I learned that they had a little help of their own. They didn't rely solely on their ancestral cooking instincts. They turned to Black chefs for guidance.</p><p>These 7 cookbooks by Black chefs have inspired my family and fed us in nutrients, joy, and spiritual sustenance. They're also helping me overcome my personal fears of cooking.</p>
Get CookingWhether you're in recovery from cooking fears like me, or are just looking to expand your culinary confidence with dishes honoring Black heritage, these Black chefs are here to support you on your journey.Turn on some music, give yourself permission to make mistakes, and throw down for yourself or your loved ones. Glorious flavors await you.
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By Tara Lohan
The conclusion to decades of work to remove a dam on the Middle Fork Nooksack River east of Bellingham, Washington began with a bang yesterday as crews breached the dam with a carefully planned detonation. This explosive denouement is also a beginning.
The History<p>The Middle Fork Nooksack drains glacier-fed headwater streams that run off the icy summit of 10,778-foot Mt. Baker. The Middle Fork joins the North Fork and then the mainstem of the Nooksack River, which travels to Bellingham Bay and Puget Sound. The entire Nooksack watershed stretches 830 square miles across Washington and into British Columbia.</p>
A Plan Comes Together<p>The Middle Fork dam is not a pool dam built for water storage. Much of the time, water flows over the top until dam operators drop a floodgate to divert water to new locations. That water travels about 14 miles through tunnel and pipeline to Mirror Lake, then Anderson Creek, and to Lake Whatcom before finally being delivered to residents' taps.</p><p>Before removing the dam, engineers had to move the water intake 700 feet upstream and situate it at an elevation that still enabled city water withdrawals throughout the year, regardless of flow conditions.</p><p>They also needed to make sure that the rushing water didn't sweep up fish and accidentally send them through the water-supply system.</p><p>"The solution required a fairly complex design in the intake structure, including a fish exit pipe out of that structure to put fish back into the river in a way that meets current environmental permit standards," explains LaCroix.</p>
Project layout for the removal of the Middle Fork Nooksack diversion dam and rebuilding of water intake. City of Bellingham<p>Despite the cost and the work, she says, being able to continue to meet their municipal water obligations while opening up habitat for threatened species has been a win-win.</p><p>"I think there's a lot of benefits to having a dam removal versus fish passage — the main one being that you get a free-flowing river that can be a dynamic ecosystem and change over time," she says. "A static fish ladder just can't provide that same level of ecosystem benefit."</p>
Restoration Success<p>Despite local authorities' championing dam removal on the Middle Fork, the project has largely flown under the radar, overshadowed in the Pacific Northwest by heated discussions about a much larger potential project — removing <a href="https://www.seattletimes.com/seattle-news/feds-reject-removal-of-4-snake-river-dams-in-key-report/" target="_blank">four federal hydroelectric dams on the lower Snake River</a>, a major tributary of the Columbia River.</p><p>Proponents of dam removal there see it as the best chance for recovering threatened salmon populations, including Chinook, which could help starving Southern Resident killer whales. Those dams also provide irrigation water, barge navigation and hydropower, so there's been more pushback against removal efforts.</p><p>Previous dam removals around the country, however, have proved successful at aiding fish recovery and river restoration.</p><p>Most notably the 1999 demolition of <a href="https://therevelator.org/edwards-dam-removal/" target="_blank">Edwards Dam on Maine's Kennebec River</a> restored the annual run of alewives, a type of herring essential to the food web. The fish run has gone from zero to 5 million in the two decades since dam removal. Blueback herring, striped bass, sturgeon and shad have also extended their reach. And the resurgence has brought back osprey, bald eagles and other wildlife, too.</p><p>The overwhelming success of river restoration on the Kennebec helped to spur a nationwide dam removal movement that's now seen 1,200 dams come down since 1999. Last year a record <a href="https://www.americanrivers.org/conservation-resource/a-record-26-states-removed-dams-in-2019/" target="_blank">90 dams</a> were removed in 26 states, including <a href="https://therevelator.org/cleveland-forest-dam-removal/" target="_blank">20 dams in California's Cleveland National Forest</a>.</p>
Spider excavators remove on dam on San Juan Creek in California's Cleveland National Forest. Julie Donnell, USFS<p>The results have been seen in the Pacific Northwest, as well, which boasts the largest dam removal thus far in the country. In 2011 and 2014, the demolition of <a href="https://therevelator.org/elwha-dam-removal/" target="_blank">two dams</a> on Elwha River, which runs through Washington's Olympic National Park, opened up 70 miles of habitat that had been blocked for a century. Scientists have started seeing all five species of salmon native to the river coming back, particularly Chinook and coho. Bull trout, they've observed, have increased in size since the dams were removal.</p>
Benefits on the Middle Fork Nooksack<p>McEwan hopes to see a similar outcome on the Middle Fork.</p><p>Like the Elwha the Middle Fork Nooksack is a relatively pristine river with little development, and dam removal is expected to provide a big boost to fish. The additional miles of spawning habitat are important, but so is the temperature of that water.</p><p>The dam removal will open access to cold upstream waters, which are ideal for salmon and getting harder to come by as climate change warms waters and reduces mountain runoff.</p><p>"This is really great for the climate change resiliency for these species," says McEwan.</p><p>Steelhead will get back 45% of their historic habitat in the river, and scientists expect Chinook populations to increase in abundance by 31%.</p><p>That <em>could</em> help Southern Resident killer whales.</p><p>"When you get to the ocean, it's a little bit of a black box in terms of what you can model and say definitively is going to help, but more fish is better for orcas," McEwan says.</p><p>Upstream habitat will see benefits, too.</p><p>Oceangoing fish like salmon enrich their bodies with carbon and nitrogen while at sea. When they return to their natal rivers to spawn and die, the marine-derived nutrients they carry back upriver become important food and fertilizer for both riverine and terrestrial ecosystems — aiding everything from trees to birds to bears.</p><p>"Once the fish start making their way back, it will start changing the whole ecological system," says Delgado.</p><p><span></span>But any ecological benefit from salmon restoration, either in the ocean or the upper watershed, won't be immediate.<br></p><p>"The population of salmon on the Middle Fork is so low that we expect it's going to take quite a while to rebound," she says. "But the big picture is that what's good for salmon is good for the region — our history and our destiny are intricately intertwined."</p><p>After decades of work, that process of restoration has finally begun.</p>
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By Katie Howell
A new tool called The Food Systems Dashboard aims to save decision makers time and energy by painting a complete picture of a country's food system. Created by the Johns Hopkins' Alliance for a Healthier World, the Global Alliance for Improved Nutrition (GAIN), and the U.N. Food and Agriculture Organization (FAO), the Dashboard compiles food systems data from over 35 sources and offers it as a public good.
By Manuela Callari
It can grow to a maximum of six inches (16 centimeters), change color depending on mood and habitat, and, like all seahorses, the White's seahorse male gestates its young. But this tiny snouted fish is under threat.
Building an Ocean Seahorse Destination<p>Seahorses are found in tropical and temperate coastal water worldwide, but are most abundant around Australia, China and the Philippines. </p><p>Trade in the tiny creatures is strictly regulated because of their use in traditional medicine, aquariums and their sale as dried curios. But because they are poor swimmers and cannot easily move elsewhere, habitat loss is a particular threat for these curious animals. </p><p>Seahorses wrap their tails around seagrass and corals to avoid being carried away on currents. They use the habitat to spawn and hide from predators such as crabs, while also feeding on riches of plankton and small crustaceans living in the reef.</p><p><span></span>Where corals aren't available, <a href="https://onlinelibrary.wiley.com/doi/abs/10.1002/aqc.1217" target="_blank">scientists</a> found seahorses taking up residence in fishing nets and old crab traps abandoned at the bottom of the ocean. </p>
Mixing With the Locals<p>Baby seahorse mortality is high in the wild because they are easily caught, so those bred in the protected environment of the aquarium weren't ready to be released into the wild until early May.</p><p>The team released 90 new arrivals into Sydney Harbor, placing some directly into the purpose-built hotels, and others onto a net that wild seahorses had already settled on.</p><p>Before setting them free, the researchers marked each young seahorse with a fluorescent tag with unique IDs inserted just beneath the skin to track how they get on in the different environments. </p><p>"The most exciting part was being able to put these animals into the wild and then go back a month later and still see them surviving and growing," said McCracken. </p><p>The seahorses will be old enough to mate and reproduce around October or November 2020. And researchers hope that by then, they will be able to breed with the wild population. </p>
Building a Global Seahorse Hotel Chain<p>With seahorses everywhere facing the loss of their coral reef homes, similar projects have sprung up in places like Greece and South Africa, home to the world's most endangered seahorse, the Knysna seahorse. </p><p>"The endangered South African seahorse is benefiting from something quite similar, even though it wasn't intentional," said Peter Teske, professor at the Department of Zoology, University of Johannesburg.</p><p>In the South African <a href="https://www.researchgate.net/publication/322649251_An_endangered_seahorse_selectively_chooses_an_artificial_structure" target="_blank">case</a>, seahorses have bedded down in "Reno mattresses" — wire cages filled with rocks — that were used to build a new marina. Researchers from NGO Knysna Basin Project found the structures acted as a refuge for the animals.<span></span></p><p><span></span>While Teske describes the seahorse hotels as "a positive news story" and a great way to create public awareness of conservation, he added that establishing artificial habitats in some areas will only prevent the extinction of local populations.</p><p>"For a complete recovery, it is necessary to give the natural habitat a chance to regenerate," said the seahorse expert. </p>
Underwater Mascot<p>In Australia, the researchers hope the project could provide an opportunity to raise awareness not only of the plight of the Sydney seahorses but the other animals with which it shares its ocean habitat.</p><p>The waters around Sydney and the east coast are rich in biodiversity and include several threatened species like the weedy seadragon — a relative of the seahorse — and the grey nurse shark. Like the seahorse, they're also under pressure from pollution, ocean traffic and habitat loss through storms and coastal construction. </p><p>"It's a good thing to get people's support and interest. The seahorses are a useful vehicle to get people concerned if the harbor is in trouble," said David Booth, professor of marine ecology at the University of Technology Sydney who is also working on the project. </p><p>The hotels have become an attraction for divers hoping to catch a glimpse of these small but near mythical creatures. </p><p>"Everyone loves seahorses," added Booth, "they are so popular." </p>
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