Designing Batteries for Easier Recycling Could Avert Looming E-Waste Crisis
By Zheng Chen and Darren H. S. Tan
As concern mounts over the impacts of climate change, many experts are calling for greater use of electricity as a substitute for fossil fuels. Powered by advancements in battery technology, the number of plug-in hybrid and electric vehicles on U.S. roads is increasing. And utilities are generating a growing share of their power from renewable fuels, supported by large-scale battery storage systems.
These trends, coupled with a growing volume of battery-powered phones, watches, laptops, wearable devices and other consumer technologies, leave us wondering: What will happen to all these batteries once they wear out?
Despite overwhelming enthusiasm for cheaper, more powerful and energy-dense batteries, manufacturers have paid comparatively little attention to making these essential devices more sustainable. In the U.S. only about 5% of lithium-ion batteries – the technology of choice for electric vehicles and many high-tech products – are actually recycled. As sales of electric vehicles and tech gadgets continue to grow, it is unclear who should handle hazardous battery waste or how to do it.
As engineers who work on designing advanced materials, including batteries, we believe it is important to think about these issues now. Creating pathways for battery manufacturers to build sustainable production-to-recycling manufacturing processes that meet both consumer and environmental standards can reduce the likelihood of a battery waste crisis in the coming decade.
Batteries pose more complex recycling and disposal challenges than metals, plastics and paper products because they contain many chemical components that are both toxic and difficult to separate.
Some types of widely used batteries – notably, lead-acid batteries in gasoline-powered cars – have relatively simple chemistries and designs that make them straightforward to recycle. The common nonrechargeable alkaline or water-based batteries that power devices like flashlights and smoke alarms can be disposed directly in landfills.
However, today's lithium-ion batteries are highly sophisticated and not designed for recyclability. They contain hazardous chemicals, such as toxic lithium salts and transition metals, that can damage the environment and leach into water sources. Used lithium batteries also contain embedded electrochemical energy – a small amount of charge left over after they can no longer power devices – which can cause fires or explosions, or harm people that handle them.
The dangers of disposing of lithium batteries improperly - Battery blamed for Guernsey recycling site blaze https://t.co/Xcs76DI520— Daniel Kinsbursky (@Daniel Kinsbursky)1533569733.0
Moreover, manufacturers have little economic incentive to modify existing protocols to incorporate recycling-friendly designs. Today it costs more to recycle a lithium-ion battery than the recoverable materials inside it are worth.
As a result, responsibility for handling battery waste frequently falls to third-party recyclers – companies that make money from collecting and processing recyclables. Often it is cheaper for them to store batteries than to treat and recycle them.
Recycling technologies that can break down batteries, such as pyrometallurgy, or burning, and hydrometallurgy, or acid leaching, are becoming more efficient and economical. But the lack of proper battery recycling infrastructure creates roadblocks along the entire supply chain.
For example, transporting used batteries over long distances to recycling centers would typically be done by truck. Lithium batteries must be packaged and shipped according to the U.S. Department of Transportation's Class 9 hazardous material regulations. Using a model developed by Argonne National Laboratory, we estimate that this requirement increases transport costs to more than 50 times that of regular cargo.
Safer and Simpler
While it will be challenging to bake recyclability into the existing manufacturing of conventional lithium-ion batteries, it is vital to develop sustainable practices for solid-state batteries, which are a next-generation technology expected to enter the market within this decade.
A solid-state battery replaces the flammable organic liquid electrolyte in lithium-ion batteries with a nonflammable inorganic solid electrolyte. This allows the battery to operate over a much wider temperature range and dramatically reduces the risk of fires or explosions. Our team of nanoengineers is working to incorporate ease of recyclability into next-generation solid-state battery development before these batteries enter the market.
Conceptually, recycling-friendly batteries must be safe to handle and transport, simple to dismantle, cost-effective to manufacture and minimally harmful to the environment. After analyzing the options, we've chosen a combination of specific chemistries in next-generation all-solid-state batteries that meets these requirements.
Our design strategy reduces the number of steps required to dismantle the battery, and avoids using combustion or harmful chemicals such as acids or toxic organic solvents. Instead, it employs only safe, low-cost materials such as alcohol and water-based recycling techniques. This approach is scalable and environmentally friendly. It dramatically simplifies conventional battery recycling processes and makes it safe to disassemble and handle the materials.
Compared to recycling lithium-ion batteries, recycling solid-state batteries is intrinsically safer since they're made entirely of nonflammable components. Moreover, in our proposed design the entire battery can be recycled directly without separating it into individual components. This feature dramatically reduces the complexity and cost of recycling them.
Our design is a proof-of-concept technology developed at the laboratory scale. It is ultimately up to private companies and public institutions, such as national laboratories or state-run waste facilities, to apply these recycling principles on an industrial scale.
Rules for Battery Recycling
Developing an easy-to-recycle battery is just one step. Many challenges associated with battery recycling stem from the complex logistics of handling them. Creating facilities, regulations and practices for collecting batteries is just as important as developing better recycling technologies. China, South Korea and the European Union are already developing battery recycling systems and mandates.
One useful step would be for governments to require that batteries carry universal tags, similar to the internationally recognized standard labels used for plastics and metals recycling. These could help to educate consumers and waste collectors about how to handle different types of used batteries.
Markings could take the form of an electronic tag printed on battery labels with embedded information, such as chemistry type, age and manufacturer. Making this data readily available would facilitate automated sorting of large volumes of batteries at waste facilities.
It is also vital to improve international enforcement of recycling policies. Most battery waste is not generated where the batteries were originally produced, which makes it hard to hold manufacturers responsible for handling it.
Such an undertaking would require manufacturers and regulatory agencies to work together on newer recycling-friendly designs and better collection infrastructure. By confronting these challenges now, we believe it is possible to avoid or reduce the harmful effects of battery waste in the future.
Zheng Chen is an Assistant Professor of Engineering, University of California San Diego.
Darren H. S. Tan is a PhD Candidate in Chemical Engineering, University of California San Diego.
Disclosure statement: Zheng Chen receives funding from the National Science Foundation. Darren H. S. Tan does not work for, consult, own shares in or receive funding from any company or organization that would benefit from this article, and has disclosed no relevant affiliations beyond their academic appointment.
Reposted with permission from The Conversation.
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By Gwen Ranniger
In the midst of a pandemic, sales of cleaning products have skyrocketed, and many feel a need to clean more often. Knowing what to look for when purchasing cleaning supplies can help prevent unwanted and dangerous toxics from entering your home.
1. Fragrance – Avoid It<p>One of the fastest ways to narrow down your product options is immediately eliminating any product that promotes a fragrance, or parfum. That scent of "fresh breeze" or lemon might initially smell good, but the fragrance does not last. What does last? The concoction of various undisclosed and unregulated chemicals that created that fragrance.</p><p>Many fragrances contain phthalates, which are linked to many health risks including reproductive problems and cancer.</p>
2. With Bleach? Do Without<p>Going scent-free should have narrowed down your options substantially – now, check the front of the remaining packaging. Any that include ammonia or chlorine bleach ought to go, as these substances are irritating and corrosive to your body. While bleach is commonly known as a powerful disinfectant, there are safer alternatives that you can use in your home, such as sodium borate or hydrogen peroxide.</p><p>While you're at it, check if there are any warnings on the label – "flammable," "use in ventilated area," etc. – if the product is hazardous, that's a red flag and should be avoided.</p>
3. Check the Back Label<p>Flip to the back of the remaining contenders and check out that ingredient list. Less is more, here. Opt for a shorter ingredient list with words you recognize and/or can pronounce.</p><p>You may notice many products do not have ingredient lists – while this doesn't necessarily mean they contain toxic ingredients, transparency is key. Feel free to look up a list online, or stick to products that are open about their ingredients.</p>
4. Ingredients to Avoid<p>We already mentioned that cleaners containing fragrance or parfum, and bleach or ammonia should be avoided, but there are other ingredients to look out for as well.</p><ul><li>Quaternary ammonium "quats" – lung irritants that contribute to asthma and other breathing problems. Also linger on surfaces long after they've been cleaned.</li><li>Parabens – Known hormone disruptor; can contribute to ailments such as cancer</li><li>Triclosan – triclosan and other antibacterial chemicals are registered with the EPA as pesticides. Triclosan is a known hormone disruptor and can also impact your immune system.</li><li>Formaldehyde – Causes irritation of eyes, nose, and throat; studies suggest formaldehyde exposure is linked with certain varieties of cancer. Can be found in products or become a byproduct of chemical reactions in the air.</li></ul>
Cleaning Products and Toxics: The Bottom Line<p>Do your research. There are many cleaning products available, but taking these steps will drastically reduce your options and help keep your home toxic-free. Protecting your home from bacteria and viruses is important, but make sure you do so in a way that doesn't introduce other health risks into the home.</p><p><em>Reposted with permission from </em><em><a href="https://www.ehn.org/how-to-shop-for-cleaning-products-while-avoiding-toxics-2648130273.html" target="_blank">Environmental Health News</a>. </em><a href="https://www.ecowatch.com/r/entryeditor/2649054624#/" target="_self"></a></p>
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Twenty-five years ago, a food called Tofurky made its debut on grocery store shelves. Since then, the tofu-based roast has become a beloved part of many vegetarians' holiday feasts.
By Jessica Corbett
A leading environmental advocacy group marked Native American Heritage Month on Wednesday by urging President-elect Joe Biden, Vice President-elect Kamala Kamala Harris, and the entire incoming administration "to honor Indigenous sovereignty and immediately halt the Keystone XL, Dakota Access, and Line 3 pipelines."
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Returning the ‘Three Sisters’ – Corn, Beans and Squash – to Native American Farms Nourishes People, Land and Cultures
By Christina Gish Hill
Historians know that turkey and corn were part of the first Thanksgiving, when Wampanoag peoples shared a harvest meal with the pilgrims of Plymouth plantation in Massachusetts. And traditional Native American farming practices tell us that squash and beans likely were part of that 1621 dinner too.
Abundant Harvests<p>Historically, Native people throughout the Americas bred indigenous plant varieties specific to the growing conditions of their homelands. They selected seeds for many different traits, such as <a href="https://emergencemagazine.org/story/corn-tastes-better/" target="_blank" rel="noopener noreferrer">flavor, texture and color</a>.</p><p>Native growers knew that planting corn, beans, squash and sunflowers together produced mutual benefits. Corn stalks created a trellis for beans to climb, and beans' twining vines secured the corn in high winds. They also certainly observed that corn and bean plants growing together tended to be healthier than when raised separately. Today we know the reason: Bacteria living on bean plant roots pull nitrogen – an essential plant nutrient – from the air and <a href="http://www.tilthalliance.org/learn/resources-1/almanac/october/octobermngg" target="_blank" rel="noopener noreferrer">convert it to a form that both beans and corn can use</a>.</p><p>Squash plants contributed by shading the ground with their broad leaves, preventing weeds from growing and retaining water in the soil. Heritage squash varieties also had spines that discouraged deer and raccoons from visiting the garden for a snack. And sunflowers planted around the edges of the garden created a natural fence, protecting other plants from wind and animals and attracting pollinators.</p><p>Interplanting these agricultural sisters produced bountiful harvests that sustained large Native communities and <a href="http://dx.doi.org/10.1353/eam.2015.0016" target="_blank">spurred fruitful trade economies</a>. The first Europeans who reached the Americas were shocked at the abundant food crops they found. My research is exploring how, 200 years ago, Native American agriculturalists around the Great Lakes and along the Missouri and Red rivers fed fur traders with their diverse vegetable products.</p>
Displaced From the Land<p>As Euro-Americans settled permanently on the most fertile North American lands and acquired seeds that Native growers had carefully bred, they imposed policies that <a href="https://doi.org/10.1086/ahr/87.2.550" target="_blank">made Native farming practices impossible</a>. In 1830 President Andrew Jackson signed the <a href="https://guides.loc.gov/indian-removal-act" target="_blank">Indian Removal Act</a>, which made it official U.S. policy to force Native peoples from their home locations, pushing them onto subpar lands.</p><p>On reservations, U.S. government officials discouraged Native women from cultivating anything larger than small garden plots and pressured Native men to practice Euro-American style monoculture. Allotment policies assigned small plots to nuclear families, further limiting Native Americans' access to land and preventing them from using communal farming practices.</p><p>Native children were forced to attend boarding schools, where they had no opportunity to <a href="https://doi.org/10.5749/jamerindieduc.57.1.0145" target="_blank">learn Native agriculture techniques or preservation and preparation of Indigenous foods</a>. Instead they were forced to eat Western foods, turning their palates away from their traditional preferences. Taken together, these policies <a href="https://kansaspress.ku.edu/978-0-7006-0802-7.html" target="_blank" rel="noopener noreferrer">almost entirely eradicated three sisters agriculture</a> from Native communities in the Midwest by the 1930s.</p>
Reviving Native Agriculture<p>Today Native people all over the U.S. are working diligently to <a href="https://www.oupress.com/books/15107980/indigenous-food-sovereignty-in-the-united-sta" target="_blank" rel="noopener noreferrer">reclaim Indigenous varieties of corn, beans, squash, sunflowers and other crops</a>. This effort is important for many reasons.</p><p>Improving Native people's access to healthy, culturally appropriate foods will help lower rates of <a href="https://www.cdc.gov/vitalsigns/aian-diabetes/index.html" target="_blank">diabetes</a> and <a href="https://www.apa.org/pi/oema/resources/ethnicity-health/native-american/obesity" target="_blank">obesity</a>, which affect Native Americans at disproportionately high rates. Sharing traditional knowledge about agriculture is a way for elders to pass cultural information along to younger generations. Indigenous growing techniques also protect the lands that Native nations now inhabit, and can potentially benefit the wider ecosystems around them.</p>
By Jake Johnson
Amid reports that oil industry-friendly former Energy Secretary Ernest Moniz remains under consideration to return to his old post in the incoming Biden administration, a diverse coalition of environmental groups is mobilizing for an "all-out push" to keep Moniz away from the White House and demand a cabinet willing to boldly confront the corporations responsible for the climate emergency.